Contamination makes aluminum oxide a priceless gem
Aluminum oxide or corundum is a commonly available material. However, trace levels of contaminates in the crystal structure of aluminum oxide, can result in priceless gems, such as rubies, sapphires, and emeralds. Rubies are corundum with chromium contaminates. It's the chromium that produces the deep red color. Next to diamonds, rubies are the most precious gems.
Sapphires come in many different colors, yellow, red, pink, and the more traditional color, blue. The blue color is
only possible when titanium and iron are both present in the structure.
The gem shown in Figure 1 was labeled a ruby at a gem show.
Figure 1
However, the X-ray diffraction pattern collected on the Rigaku MiniFlex II, shown in Gigure 2, matches corundum and the two additional phases that can be found in sapphires, mainly, rutile [TiO2] and Cronstedtite [Fe2+2Fe3+(Si,Fe3+O5)(OH)4].
Figure 2
This gem would be more appropriately called a red sapphire.
Tags: composition, MiniFlex II, powder XRD, non-destructive phase identification